What is it?

Hexabromocyclododecane (HBCD) is a brominated flame retardant, used primarily in polystyrene foams for thermal insulation in the construction industry. HBCD is also used as a flame retardant on upholsteries, wall coverings, and draperies.¹ HBCD is not known to be manufactured in Canada, but is still in use.

How does it get into the ocean?

The major pathways by which brominated flame retardants enter the marine environment are likely landfill runoff and leaching from finished products into wastewater systems.

Like other flame retardants, HBCD is persistent and bioaccumulates in food webs.² However, while regulations appear to have resulted in decreasing concentrations of other flame retardants such as PBDEs^3,4, HBCD concentrations may be increasing.⁵

Is it a problem?

Brominated flame retardants as a group are known to have toxic effects to immune, thyroid, reproductive, and neurological systems in terrestrial and aquatic organisms.^7,8

In rats, HBCD exposure has been shown to cause increases in liver weight and changes to the thyroid system ⁹, while in mice, HBCD exposure caused developmental neurotoxicity.¹⁰

FACT: HBCD concentrations increased exponentially in the eggs of rhinoceros auklets, Leach’s storm-petrels, and ancient murrelets between 1990 and 2011.⁶ Low levels of HBCD were also detected in the eggs of cormorants and herons in British Columbia starting in 2003.³

What is being done?

In 2016, HBCD was added to Canada’s Toxic Substances Regulations. As of January 1, 2017, the manufacture, use, sale, and import of HBCD, as well as building and construction materials containing HBCD were prohibited in Canada.¹¹ In 2016, the European Union also prohibited the manufacture, use, and sale of HBCD.

Canadian federal environmental quality guidelines (FEQGs) have been developed for HBCD in water and sediment.¹²

What can we do?

As individuals and organizations, we can:

• Learn more about HBCD and other brominated flame retardants using the resource links below
• Recycle and dispose of waste responsibly and according to local guidelines
• Avoid using products that contain HBCD and other contaminants of concern. The US EPA’s Safer Choice program identifies products that are safer for humans and the environment and can be used as a reference to check product ingredients.^13,14 The Green Science Policy Institute also provides information regarding consumer choices.¹⁵

More information?

¹ EC 2011. Screening Assessment Report on Hexabromocyclododecane. Environment Canada and Health Canada. November 2011. 125 p. Available: http://www.ec.gc.ca/ese-ees/7882C148-8AE4-4BA4-8555-668C49F91500/HBCD%20-%20FSAR%20-%20EN.pdf

² de Wit C.A. 2002. An overview of brominated flame retardants in the environment. Chemosphere 46: 583-624.

³ Miller A, Elliott JE, Elliott KH, Guigueno MF, Wilson LK, Lee S, Idrissi A. 2015. Brominated flame retardant trends in aquatic birds from the Salish Sea region of the west coast of North America, including a mini-review of recent trends in marine and estuarine birds. Science of the Total Environment 502: 60-69.

⁴ Ross PS, Noël M, Lambourn D, Dangerfield N, Calalmbokidis J, Jeffries S. 2013. Declining concentrations of persistent PCBs, PBDEs, PCDEs, and PCNs in harbor seals (Phoca vitulina) from the Salish Sea. Progress in Oceanography 115: 160-170.

⁵ Covaci A, Gerecke AC, Law RJ, Voorspoels S, Kohler M, Heeb NV, Leslie H, Allchin CR, de Boer J. 2006. Hexabromocyclododecanes (HBCDs) in the environment and humans: a review. Environmental Science and Technology 40: 3679-3688.

⁶ Miller A, Elliott JE, Elliott KH, Guigueno MF, Wilson LK, Lee S, Idrissi A. 2014. Spatial and temporal trends in brominated flame retardants in seabirds from the Pacific coast of Canada. Environmental Pollution 195: 48-55.

⁷ de Wit CA, Herzke D, Vorkamp K. 2010. Brominated flame retardants in the Arctic environment – trends and new candidates. Science of the Total Environment 408: 2885-2918.

⁸ Letcher  RJ, Ove Bustnes J, Dietz R, Jenssen BM, Jorgensen EH, Sonne C, Verreault J, Vijayan MM, Gabrielsen GW. 2010. Exposure and effects assessment of persistent organohalogen contaminants in arctic wildlife and fish. Science of the Total Environment. 408(15): 2995-3043.

⁹ van der Ven LTM, Verhoef A, van de Kuil T, Slob W, Leonards PEG, Visser TJ, Hamers T, Herlin M, Håkansson H, Olausson H, Piersma AH, Vos JG. 2006. A 28-day oral dose toxicity study enhanced to detect endocrine effects of hexabromocyclododecane in Wistar rats. Toxicological Sciences 94: 281-292.

¹⁰ Eriksson P, Fischer C, Wallin M, Jakobsson E, Fredriksson A. 2006. Impaired behaviour, learning and memory, in adult mice neonatally exposed to hexabromocyclododecane (HBCDD). Environmental Toxicology and Pharmacology 21: 317-322.

¹¹ ECCC 2016a. Current Regulations: Regulations Amending the Prohibition of Certain Toxic Substances Regulations, 2012 (for the addition of 5 substances) (SOR/2016-252). Environment and Climate Change Canada. Available: http://ec.gc.ca/lcpe-cepa/eng/regulations/DetailReg.cfm?intReg=226.

¹² ECCC 2016b. Canadian Environmental Protection Act, 1999 Federal Environmental Quality Guidelines: Hexabromocyclododecane (HBCD). Environment and Climate Change Canada, May 2016

¹³ US EPA 2018. Safer Choice. Available at: https://www.epa.gov/saferchoice

¹⁴ US EPA. 2014. Flame Retardant Alternatives for Hexabromocyclododecane (HBCD). Available at: https://www.epa.gov/sites/production/files/2014-06/documents/hbcd_report.pdf

¹⁵ Green Science Policy Institute. 2017. Flame Retardants. Available at: http://www.sixclasses.org/videos/flame-retardants